Pengaruh Suhu Annealing Sintesis Nanopartikel TiO2 Fasa Rutile untuk Aplikasi DSSC pada Fotosuperkapasitor
Abstract
Photosupercapacitors are integrated devices that combine dye-sensitized solar cells (DSSC) and supercapacitors. This device functions as an energy conversion as well as energy storage in one system. The photoanode is one of the important parts of the DSSC in converting photons into electrons. TiO2 semiconductor material-based photoanodes are often used because of their good light-absorbing ability. This study aims to determine the effect of annealing temperature variations on the synthesis of rutile phase TiO2 in photosupercapacitor applications. The coprecipitation method was used in the synthesis of TiO2 with variations in annealing temperature 400 ℃, 500 ℃, 600 ℃, and 700 ℃. Characterization of TiO2 structure and morphology using XRD and SEM-EDX. Fabrication of photosupercapacitors was carried out using the sandwich method. XRD results show that there are two phases formed, namely anatase and rutile phases with a tetragonal crystal system in all samples with the largest particle size of 40.5 nm at 700 ℃ annealing temperature. From the SEM-EDX results, it can be seen that the morphology of TiO2 nanoparticles tends to agglomerate and has a mass presentation of Ti in TiO2 particles of 76.08 wt%. Charge-discharge tests on the performance of AC/CB/BaTiO3 electrodes showed a specific capacitance of 15.405 F/g. J-V characterization of the photosupercapacitor showed that the ZnO/TiO2 photoanode had an efficiency of 0.08%.
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